Published August 2023 | 110 pages, 25 tables, 36 figures | Download Table of contents
Metal-organic frameworks (MOFs) are self-assembled combinations of metals and inorganic ligands that result in a relatively young class of highly ordered, porous materials. MOFs with the ability to [selectively] adsorb molecules into their pores/ on their internal surfaces.
Due to their high surface area (>7000 m2/g), extremely high porosity and favourable thermal properties, MOFs are being investigated in gas storage and separation, purification, carbon capture, utilization and storage, electrochemical energy storage and sensing. Commercial activity has grown greatly in recent years.
MOFs are highly attractive for a range of industrial applications as they use non-hazardous feedstock, are cost-effective and environmentally friendly. They are potentially key materials in industrial adsorption, storage processes and catalysis and are a leading technology candidate for carbon capture. MOFs can be used to store, separate, release or protect in a range of applications including:
- Air and water filtration.
- Carbon capture, utilization and storage.
- Gas storage and delivery, and natural gas storage and purification.
- Improved chemical separations.
- Batteries and supercapacitors.
- Food packaging.
- Anti-bacterials.
- Drug delivery.
- Fuel production.
- Solvent or heavy metal recovery.
- Adsorbents for organic pollutants.
- Water harvesting.
- Heat exchangers.
- Pharmaceuticals.
- Catalysts.
- Sensors.
- Optics & Imaging.
A number of start-ups are bringing MOF products to the market, and production volumes have increased in the past two years. Report contents include:
- Technical analysis of Metal-organic frameworks (MOFs).
- Comparative analysis with other porous materials.
- Analysis of synthesis methods.
- Applications of Metal-organic frameworks (MOFs).
- Market supply chain.
- Market map.
- Market drivers and challenges.
- MOF industry developments 2021-2023.
- Addressable markets for Metal-organic frameworks (MOFs). Markets covered include Coatings, Carbon Capture, Gas Capture, Separation and Storage, Biomedicine (Drug delivery, anti-microbials, biosensors and bioimaging), Sensors, Air and Water Filtration, Water Harvesting, Batteries and Supercapacitors, Heat Exchangers, Air Conditioning, Catalysts, Sensors, Optics & Imaging.
- Historical and current demand and estimated global market revenues to 2034, by market and region.
- Profiles of 30 companies including products, production and targeted markets. Companies profiled include Nuada, NuMat Technologies, novoMOF AG, MOFWORX and Promethean Particles.
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1 INTRODUCTION 9
- 1.1 Structure and properties 10
- 1.2 Comparison to other porous materials 14
- 1.2.1 Zeolites 15
- 1.2.2 Covalent Organic Frameworks (COFs) 16
- 1.2.3 Porous Organic Polymers (POPs) 17
- 1.3 Synthesis methods 18
- 1.3.1 Solvothermal synthesis 20
- 1.3.2 Electrochemical synthesis 20
- 1.3.3 Microwave synthesis 21
- 1.3.4 Diffusion synthesis 22
- 1.3.5 Mechanochemical synthesis 22
- 1.3.6 Sonochemical synthesis 23
- 1.3.7 Room Temperature synthesis 23
- 1.3.8 Spray Pyrolysis 24
- 1.3.9 Ionothermal synthesis 24
- 1.3.10 Layer-by-layer growth technique 24
- 1.3.11 High-throughput robotic methods 25
- 1.4 Markets and applications 26
- 1.5 Industry developments 2021-2023 27
2 MARKETS FOR METAL-ORGANIC FRAMEWORKS 28
- 2.1 Factors driving demand for MOFs 28
- 2.2 Market map 29
- 2.3 Value chain 30
- 2.4 SWOT analysis 31
- 2.5 Capture, Separation and Storage 32
- 2.5.1 Gas separation 32
- 2.5.2 Hydrogen capture and storage 32
- 2.5.3 Carbon capture and storage 34
- 2.5.3.1 DAC solid sorbents 37
- 2.6 Catalysis 44
- 2.6.1 Properties 44
- 2.6.2 Applications 44
- 2.7 Coatings 45
- 2.7.1 Properties 45
- 2.7.2 Applications 45
- 2.8 Biomedicine 46
- 2.8.1 Properties 46
- 2.8.2 Applications 47
- 2.8.2.1 Drug delivery 48
- 2.8.2.2 Antibacterials 49
- 2.8.2.3 Biosensors and bioimaging 49
- 2.9 Sensors 51
- 2.9.1 Properties 51
- 2.9.2 Applications 51
- 2.10 Air and water filtration 53
- 2.10.1 Properties 53
- 2.10.2 Applications 53
- 2.11 Water harvesting 55
- 2.11.1 Properties 55
- 2.11.2 Applications 56
- 2.12 Batteries and supercapacitors 57
- 2.12.1 Properties 57
- 2.12.2 Applications 57
- 2.13 Heat exchangers 59
- 2.13.1 Properties 59
- 2.13.2 Applications 60
- 2.14 Optics and imaging 61
- 2.14.1 Properties 61
- 2.14.2 Applications 61
- 2.15 HVAC 62
- 2.15.1 Properties 62
- 2.15.2 Applications 63
- 2.16 Global market revenues, 2018-2034 65
- 2.16.1 Curent market size 65
- 2.16.2 By end-use market 67
- 2.16.3 By region 71
- 2.16.3.1 North America 73
- 2.16.3.2 Europe 73
- 2.16.3.3 Asia Pacific 73
- 2.16.3.4 Latin America 73
- 2.16.3.5 Middle East & Africa 73
3 MOF PATENTS 74
- 3.1 Global MOF patent applications 74
- 3.2 Patenting by sector 75
- 3.3 Patenting by regional authority 76
4 COMPANY PROFILES 77 (30 company profiles)
5 EX-PRODUCERS 102
6 DISTRIBUTORS 104
7 REFERENCES 106
List of Tables
- Table 1. Example MOFs and their applications. 9
- Table 2. Summary of MOFs. 10
- Table 3. Properties of Metal-Organic Frameworks (MOFs). 10
- Table 4. Comparative analysis of Metal-Organic Frameworks (MOFs) and other porous materials. 14
- Table 5. Comparison of different synthesis methods for Metal-Organic Frameworks (MOFs). 19
- Table 6. Markets and applications of Metal-organic frameworks (MOFs). 26
- Table 7. MOF industry developments 2021-2023. 27
- Table 8. Factors affecting demand for MOFs. 28
- Table 9. Applications of MOFs in gas storage and separation. 32
- Table 10. Comparison of carbon-capture materials. 34
- Table 11. Assessment of carbon capture materials 35
- Table 12. DAC technology developers and production. 39
- Table 13. Catalytic applications of MOFs. 44
- Table 14. Applications of Metal-Organic Frameworks (MOFs) in coatings. 45
- Table 15. Biomedical applications of MOFs. 47
- Table 16. MOF sensor applications. 51
- Table 17. Applications of Metal-Organic Frameworks (MOFs) in air and water filtration. 53
- Table 18. Applications of Metal-Organic Frameworks (MOFs) in water harvesting. 56
- Table 19. Applications of Metal-Organic Frameworks (MOFs) in batteries and supecapacitors. 57
- Table 20. Applications of Metal-Organic Frameworks (MOFs) in batteries and supecapacitors. 60
- Table 21. Applications of Metal-Organic Frameworks (MOFs) in optics and imaging. 61
- Table 22. Applications of Metal-Organic Frameworks (MOFs) in HVAC. 63
- Table 23. Global market revenues for MOFs, 2018-2034, Millions USD. 65
- Table 24. Global market revenues for MOFs by market, 2018-2034, Millions USD, medium revenues estimate. 67
- Table 25. Global market revenues for MOFs by market, 2018-2034, Millions USD, high revenues estimate. 69
List of Figures
- Figure 1. Examples of typical metal−organic frameworks. 9
- Figure 2. Schematic drawing of a metal–organic framework (MOF) structure. 12
- Figure 3. Representative MOFs. 13
- Figure 4. Schematic of zeolite. 16
- Figure 5. Covalent organic frameworks (COFs) schematic representation. 16
- Figure 6. MOF synthesis methods. 18
- Figure 7. MOF synthesis methods historically. 19
- Figure 8. Solvothermal synthesis of MOFs. 20
- Figure 9. Electrochemical Synthesis method. 21
- Figure 10. Mechanochemical synthesis of MOFs. 23
- Figure 11. Market map: Metal-Organic Frameworks. 29
- Figure 12. Metal-organic frameworks (MOFs) value chain, 30
- Figure 13. SWOT analysis: MOFs market. 31
- Figure 14. Hydrogen storage. 33
- Figure 15. NuMat’s ION-X cylinders. 34
- Figure 16. Schematic of Climeworks DAC system. 37
- Figure 17. Climeworks’ first commercial direct air capture (DAC) plant, based in Hinwil, Switzerland. 37
- Figure 18. Flow diagram for solid sorbent DAC. 38
- Figure 19. Antibacterial mechanisms of metal–organic frameworks. 49
- Figure 20. Capture mechanism for MOFs toward air pollutants. 53
- Figure 21. Schematic of a MOF-based device for water harvesting. 56
- Figure 22. MOF-coated heat exchanger. 59
- Figure 23. MOFS applied in HVAC. 63
- Figure 24. Global market revenues for MOFs, 2018-2034, Millions USD. 66
- Figure 25. Global market revenues for MOFs by market, 2018-2034, Millions USD, medium revenues estimate. 68
- Figure 26. Global market revenues for MOFs by market, 2018-2034, Millions USD, high revenues estimate. 70
- Figure 27. Global market revenues for MOFs by region 2018-2034, Millions USD, conservsative revenues estimate. 71
- Figure 28. Global market revenues for MOFs by region 2018-2034, Millions USD, high revenues estimate. 72
- Figure 29. Global MOF patent applications 2001-2022. 74
- Figure 30. Patent applications by sector. 75
- Figure 31. Patent applications by authority. 76
- Figure 32. Schematic of carbon capture solar project. 78
- Figure 33. Mosaic Materials MOFs. 85
- Figure 34. CALF-20 has been integrated into a rotating CO2 capture machine (left), which operates inside a CO2 plant module (right). 96
- Figure 35. MOF-based cartridge (purple) added to an existing air conditioner. 98
- Figure 36. Molecular sieving membrane. 99
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